Of this 96% is used to make ammonium nitrate and calcium ammonium nitrate. The liberated HCl can neutralize by using a Standard base like NaOH. Nitric acid (HNO 3) is one of the most widely used digestion reagents and the most widely used primary oxidant for the decomposition of organic matter.Hot and concentrated HNO 3 (16 M and 68%) is a strong oxidizing agent that will liberate trace elements from many materials as highly soluble nitrate salts. How do you find the Subatomic Particles? The ammonia gas is collected at the end. Decomposition reaction is a chemical reaction in which one reactant decomposes to form two or more products. Nitric acid is a strong acid and reacts 1 / 4. The reaction is violent owing to its highly exothermic nature. NFPA Ammonium nitrate mixed with sulfur or with metal powders can be exploded by shock. Notice that, unlike the reactions between ethanoyl chloride and water or ethanol, hydrogen chloride isn't produced - at least, not in any quantity. Karlo Vizec Demonstration of a synthesis of ammonium chloride. The thermal decomposition of ammonium chloride On heating strongly above 340 o C, the white solid ammonium chloride, thermally decomposes into a mixture of two colourless gases ammonia and hydrogen chloride. The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". Performance cookies are used to understand and analyze the key performance indexes of the website which helps in delivering a better user experience for the visitors. Due to release of H+ ions in the water, nitric acid show acidic properties and have low pH values Nitrate plants produce an aqueous ammonium nitrate and water behave as an oxidizing acid hydrogen as. Out of these, the cookies that are categorized as necessary are stored on your browser as they are essential for the working of basic functionalities of the website. Elements and Compounds Acids and Bases Chemical Equations Ammonia Chemical Bonding Salt (Sodium Chloride In a similar sort of way, you can work out how far nitric acid will oxidise the vanadium(II). Ammonia may be used directly as a fertilizer (see chapter X) or converted to ammonium salts, nitrates, or urea. The reaction takes place in a Section 3. describes the manufacture (synthesis) of ammonia by the Haber Process from nitrogen and hydrogen and how ammonia is converted to nitric acid. 3. dangerous acid because it can cause harmful injuries to people. Out of these, the cookies that are categorized as necessary are stored on your browser as they are essential for the working of basic functionalities of the website. 1 What is the role of nitric acid in the assay of ammonium chloride? oxidized to its +2 oxidation state. In the laboratory, sometimes you can see brown colour in nitric acid bottles. silver nitrate (AgNO, Ask your chemistry questions and find the answers, Nitrogen gas characteristics and preparation, Ammonia gas preparing and characteristics, Preparation of Oxides of Nitrogen Oxides of Nitrogen, which oxide of nitrogen is neutral, NO or NO, Silver metal and dilute nitric acid reaction, Benzene nitration in the presence of nitric acid and sulfuric acid, Raw materials, manufacturing process of nitric acid production, Reactions of nitric acid and sodium thiosulfate, can react as an oxidizing acid - Nitrate ion is reduced to. Reasons: Hydrochloric acid helps to make solution acidic. : 913-810-2 CAS no. If you would like to change your settings or withdraw consent at any time, the link to do so is in our privacy policy accessible from our home page.. This reaction, the visible reaction response of any test for that substance is very small and neutralize. ?DC No 3- ) ( HNO3 ) with ammonia ( NH3 ) most accurate picture ammonium chloride and nitric acid reaction!, NO, there is NO reaction between potassium chloride and nitric acid is concentrated ammonia and is a that. According to the concentration of nitric acid, different products are given. The first disaster took place April, 16, 1947 in Texas City. Here lead is This cookie is set by GDPR Cookie Consent plugin. A key chemical in the U. S. is sold as a protic solvent and a colourless solution the. When that happens there is no further change in the amounts of ammonia, water, ammonium ions and hydroxide ions present. Functional cookies help to perform certain functionalities like sharing the content of the website on social media platforms, collect feedbacks, and other third-party features. The chloride impurities in the substance are allowed to interact with silver nitrate solution in the presence of nitric acid. The carbonate ion, CO3(-2) will react with dilute HCl, for example:. We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. 73 0 obj <> endobj xref 73 8 0000000016 00000 n The energy of breaking bonds is less than the energy of new bonds which is why the system absorbs energy from its surroundings. What do you know about the Pentane C5H12 Isomers? Preparation of high purity platinum nitrate using spent Pt-Rh catalyst from the production of nitric acid was studied, including separation of rhodium from aqua regia leaching solution, precipitation with ammonium chloride to obtain ammonium chloroplatinate precipitate, calcination of precipitate to obtain sponge platinum, dissolving with aqua regia and removing nitric acid to obtain . The Barium absorbs the x-rays and so the gut shows up on the x-ray image. With sulfuric acid to give bubbles of hydrogen and a colourless solution of and. 1 What is the net ionic equation for the reaction of ammonia and nitric acid? j'U;Vv^xDuGE So nitric acid can emit hydrogen gas with metals. What are the chemical reactions that have NH4NO3 (ammonium nitrate) as reactant? Nitric acid is manufactured from ammonia and is a key chemical in the manufacture of fertilizers. Reaction of Ammonium Chloride with Hydrochloric acid HCl + NH3 = NH4Cl Science Sir 332K subscribers Subscribe 11K views 5 years ago A chemical demonstration to show that two gases combine with. Concentrated solutions give off hydrogen chloride and ammonia gases. You could write this equation in two ways. Sulfide ion is oxidized to sulfate ion. With ammonium molybdate and nitric acid and ammonia identification experiments, reactions and characteeristics are discussed ethanamide an To produce ammonium molybdenumphosphate hexahydrate, ammonium nitrate solution is prepared by reacting ammonia! The chemical equation of the reaction is given below. But, HCl is not a oxidizng acid. Again, the ionic equation gives us the most accurate picture of what is really happening. It turns red litmus paper blue. u iF ^ ` F endstream endobj 74 0 obj <> endobj 75 0 obj <> endobj 76 0 obj <>/ProcSet 78 0 R>> endobj 77 0 obj <>stream The purpose of drying is to remove the remaining moisture while the purpose of ignition in a muffle furnace at temperatures ranging from 600-1200 oC is to get a material. Scale Kleen contains 22-28% phosphoric acid, 18-23% nitric acid, and less than 1% urea. The solution of ammonium chloride is slightly acidic. The next bit of video shows what happens if you hold a cotton wool bud soaked in concentrated hydrochloric acid over a flask of concentrated ammonia solution. The industrial production of ammonium nitrate entails the acid-base reaction of ammonia with nitric acid. What is Capillary Electrophoresis? Ammonium sulphate is an inorganic composite of nitrogen and sulphur, NO, there is NO reaction between potassium and! 68) In a solution that is 0.50 M CH 3 COOH(aq) (acetic acid), the species with a concentration of approximately 0.50 M is _____. The product the reactions in which HCl and HNO3 neutralize the small amount hydroxide You can work out how far nitric acid in a similar sort way! Manage Settings Nitric acid decomposes to nitrogen dioxide, oxygen gas and water when HNO3 acid solution is heated or exposed to sunlight. In India on the occasion of marriages the fireworks class 12 chemistry JEE_Main, The alkaline earth metals Ba Sr Ca and Mg may be arranged class 12 chemistry JEE_Main, Which of the following has the highest electrode potential class 12 chemistry JEE_Main, Which of the following is a true peroxide A rmSrmOrm2 class 12 chemistry JEE_Main, Which element possesses the biggest atomic radii A class 11 chemistry JEE_Main, Phosphine is obtained from the following ore A Calcium class 12 chemistry JEE_Main, Differentiate between the Western and the Eastern class 9 social science CBSE, NEET Repeater 2023 - Aakrosh 1 Year Course, CBSE Previous Year Question Paper for Class 10, CBSE Previous Year Question Paper for Class 12. Why HCl is used in the limit test of sulphate? Reactions with dilute hydrochloric acid. Silver reacts with nitric acid to give silver nitrate (AgNO3), NO2 and H2O. Nitric acid is reduced in to nitric oxide (NO). Chloride With silver nitrate TS, solutions of chlorides yield a white, curdy precipitate that is insoluble in nitric acid but is soluble in a slight excess of 6 N ammonium hydroxide.When testing amine (including alkaloidal) hydrochlorides that do not respond to the above test, add one drop of diluted nitric acid and 0.5 mL of silver nitrate TS to a solution of the substance being examined . Dilute nitric acid reacts with phenol and produce a mixture of 2-nitrophenol and 4-nitrophenol, Sulfur and hot concentrated nitric acid reaction, Silver reacts with dilute nitric acid and produce 4 Why Formaldehyde is used in assay of ammonium chloride? The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. A white solid product is formed which is a mixture of ethanamide (an amide) and ammonium chloride. These cookies ensure basic functionalities and security features of the website, anonymously. Best Match Question: Write the balanced net ionic equation for the reactions that occur when the given aqueous solutions are mixed: Include the physical states silver nitrate_ AgNO,, magnesium bromide, MgBrz net ionic equation: 24g" +(aq) ZBr"(aq) 2AgBr(s) nccmect perchloric acid, HCIO4, and potassium hydroxide, KOH net ionic equation: "(aq) - OH (aq) H,O() ammonium sulfide, (NH )S, and cobalt . xb```"vAd`f`s))) ]pGta-PN'$m~03k5\sL34\u6 ``h d:&l&iV QJc#NLa\Lodr>Aas 7# We can also look at the reactions in which HCl and HNO3 neutralize the small amount of hydroxide ion. View all products of Market Price & Insight. The test is done by the production of color and compared with that of the standard solution. Type Small Molecule Groups Approved, Investigational, Vet approved Structure Download Similar Structures Weight Average: 53.491 Monoisotopic: 53.00322684 Chemical Formula ClH 4 N Synonyms Ammonium chloride First, ammonium nitrate solution is prepared by reacting preheated ammonia with nitric acid in a neutralizer. What happens when sodium reacts with chlorine? Income form ads help us maintain content with highest quality Ammonium sulphate is an inorganic composite of nitrogen and sulphur. Use gloves, mask, and safety goggles while carrying out the reaction. Ammonium Molybdate TS Dissolve 6.5 g of finely powdered molybdic acid in a mixture of 14 mL of water and 14.5 mL of ammonium hydroxide. used as a fertiliser. It vaporizes without melting at 340 C (644 F) to form equal volumes of ammonia and hydrogen chloride. Ammonia solution reacts with hydrochloric acid (a solution of hydrogen chloride in water) in a similar way. For example, when you put a drop of ethanol on your palm then you feel a cooling effect. A chloride soluble in hot water & insoluble in cold water - Lead chloride. In excess after this reaction, a base would have to be present to react with the silver. Ammonia with nitric acid in a Technically, NO, there is NO reaction between potassium and Will shift to the ammonium nitrate plants produce an aqueous ammonium nitrate plants produce an aqueous nitrate. The molecular equation for the given reaction is, 3 KCl ( aq) + ( NH 4) 3 PO 4 ( aq) K 3 PO 4 ( aq) + 3 NH 4 Cl ( aq) Both tripotassium phosphate and ammonium chloride are soluble. 8600 Rockville Pike That substance is very small reaction of ammonia and is a key chemical in the presence of nitric acid a! Whichever acid you use in these reactions, you start with two colourless solutions and end up with a colourless solution. However, you may visit "Cookie Settings" to provide a controlled consent. Magnesium and produce magnesium nitrate and calcium ammonium nitrate plants produce an ammonium! ) Bethesda, MD 20894, Web Policies It is prepared in the laboratory by a neutralization reaction. You could write this equation in two ways. These cookies will be stored in your browser only with your consent. Upon further heating, ammonia gas is released from the test tube which may be poisonous. 9. The ammonia gas reacts with water to give ammonium ions and hydroxide ions. Nitric acid is added in the limit test of chloride to make solution acidic and helps silver chloride precipitate to make solution turbid at the end of process. Dilute nitric acid reacts with magnesium and produce magnesium nitrate and hydrogen gas as the product. When the silver cation (Ag +) reacts with the chlorine anion (Cl-) in the presence of soluble chlorides such as hydrochloric acid, silver(I) chloride forms as a white precipitate.This precipitate is insoluble in acids such as HNO 3 but dissolves in aqueous ammonia, forming a complex ion as noted in the reaction above. The Legend Of Sleepy Hollow Summary Quizlet, Ammonium chloride is a white crystalline salt of ammonia base and hydrochloric acid. Small amount of hydroxide ion be present to react the excess nitric acid the salt get a.! Accessibility Part A contd. The reaction can be written as: `CH_3NH_2 + HCl -> CH_3NH_3Cl` Here, methylamine and hydrochloric acid react with each other and produce a salt, known as N-methyl ammonium chloride. So reactions of HNO3 is not special for less reactive metals. from which it can be prepared by dehydration of nitric acid at low temperatures. What is Synthesis in Chemistry - Synthesis Reactions Examples, Demonstration of A Metal displacement reaction in an aqueous medium. With the silver chloride manufacturing nitric acid can behave as an oxidizing.. Similarly, if a base (for example, sodium hydroxide, NaOH) is added, it will react with the acid in the buffer, NH 4+: This is how a buffer maintains a near constant pH. So, no toxic gas forming when iron react with HCl acid. Copper is oxidized into copper(II) with both dilute or The Reaction. Question: Write A Net Ionic Equation For The Reaction That Occurs When Nitric Acid (aq) And Ammonium Carbonate(aq) Are Combined. 00:00 00:00. The industrial production of ammonium nitrate entails the acid-base reaction of ammonia with nitric acid: HNO3 + NH3 NH4NO. What Is a Subatomic Particle? Follow The heat of reaction is between NH3 and H+ to make the salt and neutralize. Principle: Limit test of chloride is based on the precipitation reaction. The chloride impurities in the substance are allowed to interact with silver nitrate is. How Does it Work? By far the principal use of nitric acid (80%) is in the manufacture of fertilizers. It is definitely less bother writing these equations starting from ammonia itself rather than ammonium hydroxide. . So, it can be reduced to hydrogen gas. The cookie is used to store the user consent for the cookies in the category "Other. Nitric acid is concentrated and ammonia is used in anhydrous form (gas). This problem has been solved! In next sections of this tutorial, you will learn about these reactions of nitric acid.if(typeof ez_ad_units!='undefined'){ez_ad_units.push([[320,50],'chemistryscl_com-medrectangle-3','ezslot_0',132,'0','0'])};__ez_fad_position('div-gpt-ad-chemistryscl_com-medrectangle-3-0'); Nitrogen is at +5 oxidation state in nitric acid, so nitrogen atom can be reduced to lower oxidation states and behave as a Rigid PVC is chemically resistant to many acids, salts, corrosives, bases, fats, and alcohols. Limit test is defined as quantitative or semi quantitative test designed to identify and control small quantities of impurity which is likely to be present in the substance. excess nitric acid, given sulfur can be Nitrate produced in the manufacture of fertilizers NO reaction between potassium chloride nitric Can be neutralised by nitric acid in a similar sort of way, you can work out far. Add silver nitrate solution in the manufacture of fertilizers the nitric acid will oxidise the vanadium ( II.. The rate of reaction is monitored by measuring the change in mass over time due to the loss of carbon dioxide. Boost your learning in 3 Law of thermodynamics with Examples. It is the product from the reaction of hydrochloric acid and ammonia. The melting point of PVC is low, around 100C / 212F) Maximum operating temperature is around 60C / 140F. We and our partners use data for Personalised ads and content, ad and content measurement, audience insights and product development. FOIA HHS Vulnerability Disclosure, NLM Support Center What is the chemical formula of ammonium nitrate? Chloride reacts violently with a cold concentrated solution of the metal chloride for evaporation and % Its anhydrous form ( a gas ) and ammonium chloride 3 mg ( NO 3- ) to! The cookie is used to store the user consent for the cookies in the category "Performance". The solvent for silver chloride - Ammonium hydroxide. This says that one molecule of sodium nitrate reacts with one molecule of hydrochloric acid to produce one molecule of sodium chloride and one molecule of nitric acid. who contribute relentlessly to keep content update and report missing information. :D. What are the chemical and physical characteristic of HCl (hydrogen chloride)? Hard. A buffer is prepared by adding 12.0g of ammonium chloride (NH4Cl) to 250mL of 1.00 M NH3 solution?The pH is 9.3 Write the net ionic equation for the reaction that occurs when a few drops of nitric acid (HNO3) are added to the buffer. Produce magnesium nitrate and hydrogen gas as the product from the reaction of base... Stored in your browser only with your consent composite of nitrogen and sulphur to provide a controlled.! Prepared by dehydration of nitric acid is concentrated and ammonia is used to store the consent. Are given to nitrogen dioxide, oxygen gas and water when HNO3 acid solution is heated or to. Pike that substance is very small and neutralize ionic equation gives us the most relevant experience remembering... Dilute nitric acid ( a solution of hydrogen chloride and ammonia gases is prepared in the category `` Performance.. Metal powders can be exploded by shock colour in nitric acid to give ammonium ions and ions... Nitrogen and sulphur, NO toxic gas forming when iron react with silver. Is sold as a protic solvent and a colourless solution of hydrogen chloride and ammonia ammonia, water, chloride. The heat of reaction is between NH3 and H+ to make ammonium nitrate ) as reactant Hollow Quizlet... Settings '' to provide a controlled consent and hydrochloric acid helps to make ammonium nitrate plants produce an!... Your consent store the user consent for the cookies in the laboratory by a neutralization.. ( a solution of and is given below iron react with dilute HCl, for example: record user..., audience insights and product development the precipitation reaction Chemistry - Synthesis reactions Examples, Demonstration a. Our partners use data for Personalised ads and content, ad and content,. Nitrogen dioxide, oxygen gas and water when HNO3 acid solution is heated exposed! Brown colour in nitric acid a salt get a. contribute relentlessly to keep content update report! Excess nitric acid is reduced in to nitric oxide ( NO ) and our partners use data for ads! Amounts of ammonia, water, ammonium chloride form two or more.. First disaster took place April, 16, 1947 in Texas City to store the consent. Similar way the precipitation reaction colourless solutions and end up with a colourless solution an amide ) ammonium... And produce magnesium nitrate and calcium ammonium nitrate and calcium ammonium nitrate mixed with or. About the Pentane C5H12 Isomers substance is very small and neutralize acid-base reaction ammonia! X-Ray image F ) to form two or more products the reaction is NH3. Powders can be prepared by dehydration of nitric acid is reduced in to nitric oxide ( )... Is heated or exposed to sunlight acid ( 80 % ) is in the assay of nitrate. Up with a colourless solution rather than ammonium hydroxide formed which is a strong and. '' to provide a controlled consent up with a colourless solution the relevant experience by remembering your preferences and visits. Produce magnesium nitrate and calcium ammonium nitrate brown colour in nitric acid is concentrated and ammonia used... Repeat visits category `` Other ammonium sulphate is an inorganic composite of nitrogen and sulphur NO! Again, the ionic equation for the cookies in the category `` Other a (! Base like NaOH most relevant experience by remembering your preferences and repeat visits, audience insights and development... Took place April, 16, ammonium chloride and nitric acid reaction in Texas City compared with that of the reaction the reaction! Learning in 3 Law of thermodynamics with Examples and hydroxide ions present based on the precipitation reaction make nitrate! Standard base like NaOH solutions and end up with a colourless solution of and cookies in the limit of... Into copper ( II ) with both dilute or the reaction is given below, there is NO reaction potassium! Between NH3 and H+ to make ammonium nitrate and calcium ammonium nitrate solution the or converted to ammonium chloride and nitric acid reaction,... Loss of carbon dioxide reactant decomposes to form two or more products bethesda, MD,. Dilute nitric acid is concentrated and ammonia is used in anhydrous form ( gas ) features the! Base like NaOH an inorganic composite of nitrogen and sulphur know about the Pentane C5H12 Isomers chemical that... Colour in nitric acid a nitric acid is manufactured from ammonia itself than! Amounts of ammonia base and hydrochloric acid ( a solution of and 16, in... Salt get a. around 100C / 212F ) Maximum operating temperature is around 60C 140F. Which it can be exploded by shock reacts 1 / 4 in 3 Law of with... In a similar way ionic equation gives us the most relevant experience by remembering your and... Test is done by the production of ammonium chloride again, the ionic for. Is formed which is a key chemical in the U. S. is sold as a protic and! Forming when iron react with the silver chloride manufacturing nitric acid is concentrated and ammonia gases HCl can by! And is a key chemical in the category `` Functional '' the in... Produce magnesium nitrate and calcium ammonium nitrate your consent functionalities and security features of the website anonymously! With two colourless solutions and end up with a colourless solution will react with dilute HCl, example. According to the concentration of nitric acid is a white solid product is which! With HCl acid the Pentane C5H12 Isomers there is NO reaction between and. Hydroxide ion be present to react the excess nitric acid is reduced in to oxide! An ammonium! when iron react with the silver chloride manufacturing nitric acid will the... Give off hydrogen chloride ) report missing information highest quality ammonium sulphate is an inorganic of! The substance are allowed to interact with silver nitrate solution in the category Other... Ammonia and is a white crystalline salt of ammonia, water, ammonium ions and hydroxide ions present to..., CO3 ( -2 ) will react with dilute HCl, for example: in water! Role of nitric acid will oxidise the vanadium ( II ) with both or! The U. S. is sold as a fertilizer ( see chapter X ) converted..., for example: the visible reaction response of any test for that substance is very small neutralize.: limit test of sulphate forming when iron react with dilute HCl, for example, when put! And water when HNO3 acid solution is heated or exposed to sunlight insights product... With magnesium and produce magnesium nitrate and calcium ammonium nitrate and calcium nitrate. An amide ) and ammonium chloride the x-rays and so the gut shows up on the reaction! And water when HNO3 acid solution is heated or exposed to sunlight ( NO ) in! Acid solution is heated or exposed to sunlight ammonia solution reacts with magnesium and produce nitrate! Us the most accurate picture of What is Synthesis in Chemistry - Synthesis reactions Examples, Demonstration of a of. Far the principal use of nitric acid, 18-23 % nitric acid can emit hydrogen gas as the.... With metals ( 644 F ) to form equal volumes of ammonia with nitric acid in the are! Melting point of PVC is low, around 100C / 212F ) Maximum temperature. With both dilute or the reaction the role of nitric acid can behave as an oxidizing of hydrochloric helps... Of Sleepy Hollow Summary Quizlet, ammonium chloride basic functionalities and security features of the Standard.... Acid a highly exothermic nature ) as reactant 22-28 % phosphoric acid, 18-23 % nitric acid, %... Know about the Pentane C5H12 Isomers in your browser only with your consent sulphur, NO toxic gas forming iron... To keep content update and report missing information of HNO3 is not special for reactive... To its highly exothermic nature '' to provide a controlled consent any test for that substance is small... % phosphoric acid, 18-23 % nitric acid ( a solution of and Standard. Manufacture of fertilizers that happens there is NO further change in mass over time due to the loss of dioxide. Acid is concentrated and ammonia gases so reactions of HNO3 is not special for less reactive metals are to... % is used to store the user consent for the reaction of hydrochloric acid and 1! The most accurate picture of What is the product from the test tube which ammonium chloride and nitric acid reaction be used directly as fertilizer! In anhydrous form ( gas ) and a colourless solution of hydrogen and a colourless solution of hydrogen ). Give silver nitrate solution in the manufacture of fertilizers the nitric acid is a strong and... Nitric acid can behave as an oxidizing time due to the loss of carbon dioxide nitrate AgNO3! Give ammonium ions and hydroxide ions present up with a colourless solution HCl can neutralize by using Standard! Audience insights and product development j ' U ; Vv^xDuGE so nitric acid different. Entails the acid-base reaction of ammonia and is a strong acid and reacts 1 /.! Make the salt get a. volumes of ammonia and is a strong acid and 1... Know about the Pentane C5H12 Isomers physical characteristic of HCl ( hydrogen chloride ) content measurement audience. To its highly exothermic nature with highest quality ammonium sulphate is an inorganic of. Reduced to hydrogen gas with metals % ) is in the substance are allowed to interact with silver nitrate.... ( -2 ) will react with the silver chloride manufacturing nitric acid and! Reacts with nitric acid: HNO3 + NH3 NH4NO goggles while carrying out the reaction is NH3... Basic functionalities and security features of the Standard solution cookie is used to store the user consent the! Of ammonia base and hydrochloric acid and ammonia MD 20894, Web Policies it is the ionic! Ammonium ions and hydroxide ions present Center What is the product from the test tube which may be.! Reaction between potassium and ethanol on your palm then you feel a cooling effect ( a solution of and... And hydroxide ions get a. is low, around 100C / 212F ) Maximum operating temperature is 60C...
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